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    Separation of Plastic Waste Collected Before Recycling
    High School Lab Experiments & Background Information
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    This experiment is courtesy of 

    Separation Before Plastic Recycling


    Developers:

    Sister Frances Boyle RSM
    West Catholic High School
    Archdiocese of Philadelphia

    Dr. Eugene Dougherty
    Rohm and Haas Company
    Bristol, PA


    Grade Levels:

    Grades 10 through 12


    Disciplines:

    Chemistry, Physics


    Goals:

    To give students the opportunity to see that plastics can be separated and identified by their different physical properties.


    Specific Objectives:

     

    The student will:

    1. participate in a demonstration of the different densities of plastics.
    2. use density to identify an unknown plastic.
    3. suggest a method by which municipalities could separate the plastic waste collected.


    Background:

     

    On TV, plastics from milk, soda and other food containers are shown recycled into park benches and plastic posts. However, for plastics to be recycled for some uses, the plastics must be the same type. A chemical company producing plastics, such as Rohm and Haas, knows the identity of its plastic waste. The waste may not meet their color specifications but it can be sold for manufacturing where color is not critical.


    Introduction:

    Many municipalities have days when they pick up scrap metal, glass and plastics . Some communities are urged to put the three in separate containers, but even then some objects appear in the wrong category of waste. How is the waste separated for recycling? Trash on a conveyer belt allows magnets to remove some metals. Other metals and glass of various colors are sorted by hand.

    How can the plastics be separated? Magnets cannot be used. Visual inspection, even with the aid of recycling codes is tedious. Can DENSITY help?


    Teacher Demonstration:

    Apparatus:  seven (7) 250-mL beakers, graduated cylinders, stirring rod, long forceps

    Material:  Listed in the following chart.

    Prepare the seven (7) beakers with the liquids in the following chart. Demonstrate how samples of plastic sink or float in the appropriate liquids.


    After a discussion of solution proportions and %, students made up the solutions. The separation worked well.

    Densities of Polymers and Seperating Liquids*

    Kenneth E. Kolb and Doris K. Kolb,Bradley University, Peoria, IL 61625
    Journal of Chemical Education


     

    Apparatus:

    Materials:

    Procedure:

    Student Laboratory Procedures: (DONE IN GROUPS OF 4)

    250-mL beaker, forceps

    distilled water
    two (2) plastic samples (with coded identity) for each group
    access to beakers previously used in demonstration

    1. Assign one (1) piece of plastic to each pair in group of four (4).

    2. Examine the plastic and record its code and its appearance.

    Sample Code __________________ Sample Code __________________

    Appearance ___________________ Appearance ___________________

    3. Plan how to use what you learned from teacher demonstration and he apparatus and materials you have been assigned to identify the pieces of plastic. Students have access to all beakers from previous demonstration. Also they have access to distilled water and normal laboratory equipment.

    4. Each team executes the identification plan for the piece of plastic you have been given. Have the other pair verify your identification. Fill in the identification below.

    Sample Code _________________ Sample Code __________________

    Sample Identify _______________ Sample Identify________________

    5. Using words, pictures or a physical model, show how a municipality could separate the large volume of waste plastics it collects.


    Additional Information:

     

    Chemical companies such as Rohm and Haas are working on processes that would reduce various plastic waste to original monomers. Therefore, sepa- ration before recycling would be unnecessary.

    Petroleum refineries, such as Amoco Chemical Co. (Naperville, IL) convert plastic waste into basic chemicals. Some efforts to reuse plastic waste have focused on burning the waste for energy.

    Plastics can also be separated by differences in solubilities. Several articles in the Journal of Chemical Education are helpful here. In Volume 60, No. 2, February 1983, Joseph H. Ross of Indiana University at South Bend, IN 46634 wrote "Demonstration of Solvent Differences by Visible Polymer Swelling." In Volume 62, No. 9, September 1985, Helene Cloutier and Robert E. Prud'homme of Laval University, Quebec 10, P.Q. Canada G1K7P4 included the following chart in their article "Rapid Identification of Thermoplastic Polymers":

    The table below is taken from SHOPPING FOR PLASTICS developed by Lisa Ann Jones et al for PROJECT LABS and published in the fall of 1990.

    Here is a sample list of items which bear the plastics recycling symbol and code.

    1-PETE

    2-HDPE

    3-V

    4-LDPE

    mouthwash
    Pepto Bismol�
    soda
    spices
    peanut butter
    salad dressing
    seltzer
    coffee
    bacon bits

    Cool Whip�
    lemonade
    grated cheese
    Hershey syrup�
    detergents
    mini-juices
    water bottles
    bath cleaners
    milk bottles

    car wax
    peanut oil
    Ajax liquid�
    Cremora�
    clear shampoo
    Rit� dye

    mustard
    diapers (package)

    5-PP

    6-PS

    7-OTHER

    Rubbermaid�
    salsa
    alfredo sauce
    solid detergents
    syrup
    yogurt

    salad containers
    cheese containers
    cottage cheese
    petroleum jelly

    ketchup
    plastic cups
    juice bottles
    cat food


    This experiment is courtesy of 



    My Dog Kelly

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